Short-range magnetic order and temperature-dependent properties of cupric oxide.
نویسندگان
چکیده
The temperature dependence of the optical and magnetic properties of CuO were examined by means of hybrid density functional theory calculations. Our work shows that the spin exchange interactions in CuO are neither fully one-dimensional nor fully three-dimensional. The temperature dependence of the optical band gap and the (63)Cu nuclear quadrupole resonance frequency of CuO originate from the combined effect of a strong coupling between the spin order and the electronic structure and the progressive appearance of short-range order with temperature.
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عنوان ژورنال:
- Journal of physics. Condensed matter : an Institute of Physics journal
دوره 22 4 شماره
صفحات -
تاریخ انتشار 2010